Structural and photophysical studies of phenanthrene adducts involving C6F5HgCl and [o-C6F4Hg]3.
نویسندگان
چکیده
Both pentafluorophenylmercury chloride and trimeric perfluoro-ortho-phenylene mercury interact with phenanthrene to form phosphorescent adducts which exhibit extended binary stacks in the solid state.
منابع مشابه
Supramolecular aggregation of Ni(salen) with (C6F5)2Hg and [o-C6F4Hg]3.
As part of our ongoing interest in the supramolecular chemistry of fluorinated organomercurials, we have investigated the interaction of bis(pentafluorophenyl)mercury ((C6F5)2Hg), and trimeric (perfluoro-o-phenylene)mercury ([o-C6F4Hg]3), with nickel(II) N,N'-bis(salicylidene)ethylenediamine) (Ni(salen)). While solution studies monitored by UV-VIS spectroscopy suggest that Ni(salen) interacts w...
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Reactions of the cyclo-E5 sandwich complexes [Cp*Fe(η5-P5)] (1) and [Cp*Fe(η5-As5)] (2) with the planar Lewis acid trimeric (perfluoro-ortho-phenylene)mercury [(o-C6F4Hg)3] (3) afford compounds that show distinctly different assemblies in the solid state. The phosphorus containing ligand 1 forms dimeric coordination units with two molecules of 3, with one P atom of each cyclo-P5 ligand position...
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ورودعنوان ژورنال:
- Dalton transactions
دوره 39 شماره
صفحات -
تاریخ انتشار 2006